On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study.
نویسندگان
چکیده
The prevalence of a counterintuitive carbene conformation in a series of piano-stool Mn(I) alkylalkoxycarbene complexes was rationalized by means of DFT calculations and high-resolution XRD analysis in terms of stabilizing non-covalent C-H···C≡O interligand interactions.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 4 شماره
صفحات -
تاریخ انتشار 2013